Study of alkene epoxidation in the presence of extruded silicalite titanium

A. V. Sulimov; A. V. Ovcharova; A. A. Ovcharov; V. R. Flid; S. V. Leont’eva; L. G. Bruk; Zh. Yu. Pastukhova; M. R. Flid

doi:10.1007/s11172-016-1666-7

Study of alkene epoxidation in the presence of extruded silicalite titanium

Authors: Sulimov A.V.¹, Ovcharova A.V.¹, Ovcharov A.A.¹, Flid V.R.², Leont’eva S.V.², Bruk L.G.², Pastukhova Z.Y.², Flid M.R.³
Affiliations:
1. R. E. Alekseev Nizhny Novgorod State Technical University
2. Moscow Technological University (Institute of Fine Chemical Technologies)
3. Research Engineering Center Syntez
Issue: Vol 65, No 12 (2016)
Pages: 2845-2849
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/239531
DOI: https://doi.org/10.1007/s11172-016-1666-7
ID: 239531

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Abstract

Main features of liquid-phase epoxidation of propylene, allyl chloride, and allyl alcohol by aqueous solution of hydrogen peroxide in the presence of extruded titanium silicalite in methanol medium have been investigated. The effects of the solvent, the initial ratio of the organic substrate: hydrogen peroxide, and temperature on the yield of main products and by-products were elucidated. Based on the obtained features the conditions for the synthesis of propylene oxide, epichlorohydrin, and glycidol in a laboratory continuous set-up were established.

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Study of alkene epoxidation in the presence of extruded silicalite titanium

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Abstract

About the authors

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