Email this article Reaction of polymethine dyes with hydroperoxides and free radicals
- Authors: Zinatullina K.M.1,2, Kasaikina O.T.2,3, Kuzmin V.A.1,3, Khrameeva N.P.1, Shapiro B.I.1
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Affiliations:
- N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
- N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Issue: Vol 65, No 12 (2016)
- Pages: 2825-2831
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239516
- DOI: https://doi.org/10.1007/s11172-016-1663-x
- ID: 239516
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Abstract
The interaction kinetics of the cationic and anionic polymethine dyes with radicals has been studied. Azoinitiator AAPH, as well as tert-butyl hydroperoxide, and hydrogen peroxide were used as radical initiators in water and buffer solutions at 37 °C. It is shown that the dyes are active scavengers of peroxyl radicals. It is found that reactivity and behavior of dyes in relation to the peroxides are strongly dependent on the structure of lateral substituents in polymethine chains.
About the authors
K. M. Zinatullina
N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences; N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Email: okasai@yandex.ru
Russian Federation, 4 ul. Kosygina, Moscow, 119991; 4 ul. Kosygina, Moscow, 119991
O. T. Kasaikina
N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences; Department of Chemistry, M. V. Lomonosov Moscow State University
Author for correspondence.
Email: okasai@yandex.ru
Russian Federation, 4 ul. Kosygina, Moscow, 119991; Build. 3, 1 Leninskie Gory, Moscow, 119992
V. A. Kuzmin
N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences; Department of Chemistry, M. V. Lomonosov Moscow State University
Email: okasai@yandex.ru
Russian Federation, 4 ul. Kosygina, Moscow, 119991; Build. 3, 1 Leninskie Gory, Moscow, 119992
N. P. Khrameeva
N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Email: okasai@yandex.ru
Russian Federation, 4 ul. Kosygina, Moscow, 119991
B. I. Shapiro
N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Email: okasai@yandex.ru
Russian Federation, 4 ul. Kosygina, Moscow, 119991
