Email this article Synthesis of 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide
- Authors: Guskov A.A.1, Klenov M.S.1, Churakov A.M.1, Tartakovsky V.A.1
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Issue: Vol 65, No 11 (2016)
- Pages: 2763-2765
- Section: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/239475
- DOI: https://doi.org/10.1007/s11172-016-1650-2
- ID: 239475
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Abstract
5-Amino-(tert-butyl-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide reacts with nitronium tetra-fluoroborate to give 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide. This compound is of interest as a new energetic material. A plausible reaction mechanism involves electrophilic substitution of the tert-butyl-NNO-azoxy group by the nitro group.
About the authors
A. A. Guskov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: churakov@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
M. S. Klenov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: churakov@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. M. Churakov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: churakov@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
V. A. Tartakovsky
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: churakov@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
