Enviar artigo por via de e-mail Reactions of gem-difluoro-substituted organozinc reagents with propargyl halides
- Autores: Zemtsov A.A.1, Kondratyev N.S.1, Levin V.V.1, Struchkova M.I.1, Dilman A.D.1
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Afiliações:
- N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Scienses
- Edição: Volume 65, Nº 11 (2016)
- Páginas: 2760-2762
- Seção: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/239472
- DOI: https://doi.org/10.1007/s11172-016-1649-8
- ID: 239472
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Resumo
gem-Difluoro-substituted organozinc reagents undergo cross-coupling reaction with propargyl halides in the presence of catalytic amounts of copper cyanide. The reaction leads to the formation of 4,4-difluoroallenes in high yields.
Sobre autores
A. Zemtsov
N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Scienses
Email: dilman@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
N. Kondratyev
N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Scienses
Email: dilman@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
V. Levin
N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Scienses
Email: dilman@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
M. Struchkova
N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Scienses
Email: dilman@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
A. Dilman
N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Scienses
Autor responsável pela correspondência
Email: dilman@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
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