Cocrystallization of diastereomers in the series of 2(5H)-furanone bis-thioethers based on 1,2-phenylenedimethanethiol


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Abstract

Crystallization of diastereomeric mixtures of 2(5H)-furanone bis-thioethers, in the molecules of which two unsaturated γ-lactone rings are bound by 1,2-phenylenedimethanethiol bridge through their carbon atoms C(4), was studied. A rare case of cocrystallization of meso- and d,l-diastereomers for bis-thioethers with the small-size methoxy or hydroxy substituents at the asymmetric carbon atom was observed.

About the authors

O. A. Lodochnikova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; A. M. Butlerov Institute of Chemistry, Kazan Federal University

Author for correspondence.
Email: olga@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlevskaya, Kazan, 420008

L. T. Hoang

A. M. Butlerov Institute of Chemistry, Kazan Federal University

Email: olga@iopc.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008

A. R. Zaripova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; A. M. Butlerov Institute of Chemistry, Kazan Federal University

Email: olga@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlevskaya, Kazan, 420008

A. R. Kayumov

Institute of Fundamental Medicine and Biology, Kazan Federal University

Email: olga@iopc.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008

I. A. Litvinov

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: olga@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088

A. R. Kurbangalieva

A. M. Butlerov Institute of Chemistry, Kazan Federal University

Email: olga@iopc.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008


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