Complexation of dirhodium(II) with N-functionalized calix[4]resorcinarenes
- Autores: Guseva E.V.1, Buslaeva T.M.2, Grishin E.I.1
-
Afiliações:
- Kazan National Research Technological University
- Moscow Technological University (Institute of Fine Chemical Technology)
- Edição: Volume 65, Nº 10 (2016)
- Páginas: 2485-2493
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239207
- DOI: https://doi.org/10.1007/s11172-016-1611-9
- ID: 239207
Citar
Resumo
Some features of the complexation of [Rh2(OAc)4•2H2O] with calix[4]resorcinarenes functionalized by aminoalkyl groups in the upper or lower rims in EtOH and Me2CO are considered. The properties of complexes were studied by IR, UV—Vis, Raman, ESR, 1H NMR spectroscopies, simultaneous thermal analysis, and conductommetry. It is shown that the way of coordination of calixresorcinarene matrix to the central atom, either through the donor nitrogen atoms of outer aminoalkyl groups or through oxygen atoms of resorcinarene groups, is determined by conformation and configuration capabilities of the ligands and the nature of the solvent.
Palavras-chave
Sobre autores
E. Guseva
Kazan National Research Technological University
Email: buslaevatm@mail.ru
Rússia, 68 ul. Karla Marksa, Kazan, 420015
T. Buslaeva
Moscow Technological University (Institute of Fine Chemical Technology)
Autor responsável pela correspondência
Email: buslaevatm@mail.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571
E. Grishin
Kazan National Research Technological University
Email: buslaevatm@mail.ru
Rússia, 68 ul. Karla Marksa, Kazan, 420015
Arquivos suplementares
