Modeling of electrochemical processes in solid oxide fuel cells
- Authors: Volokhov V.M.1, Averkov I.S.2, Baykov A.V.2,1, Yanovskiy L.S.2,1
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- P. I. Baranov Central Institute of Aviation Motors
- Issue: Vol 65, No 10 (2016)
- Pages: 2375-2380
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239061
- DOI: https://doi.org/10.1007/s11172-016-1592-8
- ID: 239061
Cite item
Abstract
A mathematical model of electrochemical processes in a solid oxide fuel cell is presented. A procedure for the calculation of the current—voltage characteristic (CVC) taking into account the influence of the reagent concentration, pressure, and temperature is considered. The problem of calculation of the electromotive force (emf) and thermodynamic efficiency was studied in detail. The influence of the presence of carbon dioxide and water vapor in the anode gas on the emf and thermodynamic efficiency is analyzed. The method of measuring the CVC in an experiment at a constant fuel rate is briefly considered. The results of application of the calculation model are compared with the experimental data.
About the authors
V. M. Volokhov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: averkov@ciam.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
I. S. Averkov
P. I. Baranov Central Institute of Aviation Motors
Author for correspondence.
Email: averkov@ciam.ru
Russian Federation, 2 ul. Aviamotornaya, Moscow, 111116
A. V. Baykov
P. I. Baranov Central Institute of Aviation Motors; Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: averkov@ciam.ru
Russian Federation, 2 ul. Aviamotornaya, Moscow, 111116; 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
L. S. Yanovskiy
P. I. Baranov Central Institute of Aviation Motors; Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: averkov@ciam.ru
Russian Federation, 2 ul. Aviamotornaya, Moscow, 111116; 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432