Synthesis and investigation of novel poly( p -arylenevinylene)s containing 2-substituted pyrimidine fragments

E. A. Komissarova; I. V. Lunegov; O. A. Mayorova; E. V. Shklyaeva; G. G. Abashev

doi:10.1007/s11172-016-1580-z

Synthesis and investigation of novel poly(p-arylenevinylene)s containing 2-substituted pyrimidine fragments

Authors: Komissarova E.A.¹^,2, Lunegov I.V.¹, Mayorova O.A.², Shklyaeva E.V.³, Abashev G.G.²
Affiliations:
1. Perm State University
2. Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences
3. Institute of Natural Science, Perm State University
Issue: Vol 65, No 9 (2016)
Pages: 2291-2298
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/239004
DOI: https://doi.org/10.1007/s11172-016-1580-z
ID: 239004

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Abstract
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Abstract

New 2-alkoxy- and 2-alkylthio-4,6-di(bromomethyl)pyrimidines have been synthesized and polymerized via Gilch approach. Optical and electrochemical properties of thus prepared conjugated polymers in solutions were investigated. The thin films were prepared by spin-coating and casting. The film structure was studied with the help of scanning tunneling microscopy (STM).

About the authors

E. A. Komissarova

Perm State University; Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences

Email: lunegov@psu.ru
Russian Federation, 15 ul. Bukireva, Perm, 614990; 3 ul. Acad. Koroleva, Perm, 6149013

I. V. Lunegov

Perm State University

Author for correspondence.
Email: lunegov@psu.ru
Russian Federation, 15 ul. Bukireva, Perm, 614990

O. A. Mayorova

Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences

Email: lunegov@psu.ru
Russian Federation, 3 ul. Acad. Koroleva, Perm, 6149013

E. V. Shklyaeva

Institute of Natural Science, Perm State University

Email: lunegov@psu.ru
Russian Federation, 4 ul. Genkelya, Perm, 614990

G. G. Abashev