Stereoselective synthesis of 1,3-disubstituted phthalans by cyclization of (1S)-1-{2-[hydroxy(diaryl)methyl]phenyl}ethanols
- Авторы: Shishkina I.N.1, Sokolovskaya E.Y.1, Demyanovich V.M.1
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Учреждения:
- Chemical department, M. V. Lomonosov Moscow State University
- Выпуск: Том 65, № 9 (2016)
- Страницы: 2229-2232
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238954
- DOI: https://doi.org/10.1007/s11172-016-1573-y
- ID: 238954
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Аннотация
Cyclization of pure enantiomers of 1-{2-[hydroxy(diaryl)methyl]phenyl}ethanol proceeds stereoselectively and affords 1,3-disubstituted 1,3-dihydroisobenzofurans (phthalans) in moderate-to-high enantiomeric (81.7% ee) or diastereomeric (72% de) purity.
Об авторах
I. Shishkina
Chemical department, M. V. Lomonosov Moscow State University
Email: demyan@org.chem.msu.ru
Россия, 1/3 Leninskie Gory, Moscow, 119991
E. Sokolovskaya
Chemical department, M. V. Lomonosov Moscow State University
Email: demyan@org.chem.msu.ru
Россия, 1/3 Leninskie Gory, Moscow, 119991
V. Demyanovich
Chemical department, M. V. Lomonosov Moscow State University
Автор, ответственный за переписку.
Email: demyan@org.chem.msu.ru
Россия, 1/3 Leninskie Gory, Moscow, 119991
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