Stereoselective synthesis of 1,3-disubstituted phthalans by cyclization of (1S)-1-{2-[hydroxy(diaryl)methyl]phenyl}ethanols
- 作者: Shishkina I.N.1, Sokolovskaya E.Y.1, Demyanovich V.M.1
- 
							隶属关系: 
							- Chemical department, M. V. Lomonosov Moscow State University
 
- 期: 卷 65, 编号 9 (2016)
- 页面: 2229-2232
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238954
- DOI: https://doi.org/10.1007/s11172-016-1573-y
- ID: 238954
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详细
Cyclization of pure enantiomers of 1-{2-[hydroxy(diaryl)methyl]phenyl}ethanol proceeds stereoselectively and affords 1,3-disubstituted 1,3-dihydroisobenzofurans (phthalans) in moderate-to-high enantiomeric (81.7% ee) or diastereomeric (72% de) purity.
作者简介
I. Shishkina
Chemical department, M. V. Lomonosov Moscow State University
														Email: demyan@org.chem.msu.ru
				                					                																			                												                	俄罗斯联邦, 							1/3 Leninskie Gory, Moscow, 119991						
E. Sokolovskaya
Chemical department, M. V. Lomonosov Moscow State University
														Email: demyan@org.chem.msu.ru
				                					                																			                												                	俄罗斯联邦, 							1/3 Leninskie Gory, Moscow, 119991						
V. Demyanovich
Chemical department, M. V. Lomonosov Moscow State University
							编辑信件的主要联系方式.
							Email: demyan@org.chem.msu.ru
				                					                																			                												                	俄罗斯联邦, 							1/3 Leninskie Gory, Moscow, 119991						
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