Selective aerobic oxidation of cyclohexyl- and  sec -alkylarenes to hydroperoxides in the presence of  N -hydroxyphthalimide

E. A. Kurganova; V. N. Sapunov; G. N. Koshel; A. S. Frolov

doi:10.1007/s11172-016-1560-3

Selective aerobic oxidation of cyclohexyl- and sec-alkylarenes to hydroperoxides in the presence of N-hydroxyphthalimide

Autores: Kurganova E.A.¹, Sapunov V.N.², Koshel G.N.¹, Frolov A.S.¹
Afiliações:
1. Yaroslavl State Technical University
2. D. I. Mendeleev Russian University of Chemistry and Technology
Edição: Volume 65, Nº 9 (2016)
Páginas: 2115-2128
Seção: Reviews
URL: https://journals.rcsi.science/1066-5285/article/view/238900
DOI: https://doi.org/10.1007/s11172-016-1560-3
ID: 238900

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Resumo

The review summarizes the available scientific and technical information on aerobic oxidation of cyclohexyl- and sec-alkylarenes to tertiary hydroperoxides in the presence of N-hydroxyphthalimide. Kinetics, oxidation mechanism, catalytic and initiating ability of N-hydroxyphthalimide were discussed.