Radical decomposition reactions: factors affecting transition-state energetics and geometries
- Autores: Denisov E.T.1, Pokidova T.S.1
- 
							Afiliações: 
							- Institute of Problems of Chemical Physics, Russian Academy of Sciences
 
- Edição: Volume 65, Nº 8 (2016)
- Páginas: 1910-1929
- Seção: Reviews
- URL: https://journals.rcsi.science/1066-5285/article/view/238694
- DOI: https://doi.org/10.1007/s11172-016-1532-7
- ID: 238694
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Resumo
The enthalpies, activation energies, and geometries of transition states of the decomposition of organic radicals, viz., alkyl, alkoxyl, acyl, peroxyl, etc., are reviewed. The results of semiempirical and quantum chemical calculations are compared with experimental data. Special attention is given to an analysis of physicochemical factors affecting the activation barriers and geometry of transition states of radical decomposition.
Sobre autores
E. Denisov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
							Autor responsável pela correspondência
							Email: det@icp.ac.ru
				                					                																			                												                	Rússia, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
T. Pokidova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
														Email: det@icp.ac.ru
				                					                																			                												                	Rússia, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
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