Radical decomposition reactions: factors affecting transition-state energetics and geometries


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The enthalpies, activation energies, and geometries of transition states of the decomposition of organic radicals, viz., alkyl, alkoxyl, acyl, peroxyl, etc., are reviewed. The results of semiempirical and quantum chemical calculations are compared with experimental data. Special attention is given to an analysis of physicochemical factors affecting the activation barriers and geometry of transition states of radical decomposition.

Sobre autores

E. Denisov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Autor responsável pela correspondência
Email: det@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

T. Pokidova

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: det@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

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