Email this article Photochemical cyclocondensation of 1-arylthio-2-azidoanthraquinones with phenols
- Authors: Klimenko L.S.1, Sirazhetdinova N.S.1, Savel’ev V.A.2, Martyanov T.P.3, Korchagin D.V.3
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Affiliations:
- Yugra State University
- N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Issue: Vol 65, No 7 (2016)
- Pages: 1814-1819
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238593
- DOI: https://doi.org/10.1007/s11172-016-1515-8
- ID: 238593
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Abstract
Photolysis of 1-arylthio-2-azidoanthraquinones in DMSO in the presence of phenols leads to the formation of 5H-naphtho[2,3-c]phenothiazine-8,13-diones, in which the nitrogen atom is covalently bonded with the phenyl ring of the introduced phenol. As a result, poorly available polycyclic phenothiazine derivatives were obtained in one step in high yields. The cyclo-condensation with phenols was found to proceed only photochemically.
About the authors
L. S. Klimenko
Yugra State University
Author for correspondence.
Email: L_Klimenko@ugrasu.ru
Russian Federation, 16 ul. Chekhova, Khanty-Mansiisk, 6280012
N. S. Sirazhetdinova
Yugra State University
Email: L_Klimenko@ugrasu.ru
Russian Federation, 16 ul. Chekhova, Khanty-Mansiisk, 6280012
V. A. Savel’ev
N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: L_Klimenko@ugrasu.ru
Russian Federation, 9 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
T. P. Martyanov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: L_Klimenko@ugrasu.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
D. V. Korchagin
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: L_Klimenko@ugrasu.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
