Selective fluorination of pyridine and its derivatives in the presence of high-oxidation-state transition metals
- 作者: Gryaznova T.V.1, Khrizanforova V.V.1, Kholin K.V.1, Khrizanforov M.N.1, Budnikova Y.H.1
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隶属关系:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- 期: 卷 65, 编号 7 (2016)
- 页面: 1798-1804
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238582
- DOI: https://doi.org/10.1007/s11172-016-1513-x
- ID: 238582
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详细
The oxidative fluorination of pyridine and 4-ethylpyridine under chemical and electro-chemical conditions in the presence of transition metal (high-oxidation-state nickel, cobalt, and silver) salts was studied. The chemical fluorination affords 2-fluoropyridine in all cases, while the electrochemical fluorination results in 2-fluoroor 3-fluoropyridine depending on the catalyst used.
作者简介
T. Gryaznova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
V. Khrizanforova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
K. Kholin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
M. Khrizanforov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
Yu. Budnikova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
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