Selective fluorination of pyridine and its derivatives in the presence of high-oxidation-state transition metals


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The oxidative fluorination of pyridine and 4-ethylpyridine under chemical and electro-chemical conditions in the presence of transition metal (high-oxidation-state nickel, cobalt, and silver) salts was studied. The chemical fluorination affords 2-fluoropyridine in all cases, while the electrochemical fluorination results in 2-fluoroor 3-fluoropyridine depending on the catalyst used.

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T. Gryaznova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

V. Khrizanforova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

K. Kholin

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

M. Khrizanforov

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

Yu. Budnikova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

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