Synthesis, structure, and luminescent properties of PrIII complexes with pyrazole-derived 1,3-diketone and 1,10-phenanthroline


如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The interaction of PrCl3 with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione in aqueous ethanol in the presence of a base and 1,10-phenanthroline was studied. It was shown that the composition of the products was dependent on the reaction conditions. The solvate [Pr(L)3(Phen)]•3PriOH crystallizes in a monoclinic crystal system (P21/c space group, a = 12.2239(12) Å, b = 20.3403(19) Å, c = 26.134(3) Å, β = 102.380(2)° at 150 K). Absorption spectra of the complex in solution, as well as the spectra and the kinetic parameters of photo-luminescence were investigated.

作者简介

M. Metlin

P. N. Lebedev Physical Institute, Russian Academy of Sciences

Email: taidakov@gmail.com
俄罗斯联邦, 53 Leninsky prosp., Moscow, 119991

S. Ambrozevich

P. N. Lebedev Physical Institute, Russian Academy of Sciences

Email: taidakov@gmail.com
俄罗斯联邦, 53 Leninsky prosp., Moscow, 119991

S. Krasnosel’sky

P. N. Lebedev Physical Institute, Russian Academy of Sciences

Email: taidakov@gmail.com
俄罗斯联邦, 53 Leninsky prosp., Moscow, 119991

A. Vitukhnovsky

P. N. Lebedev Physical Institute, Russian Academy of Sciences; Moscow Institute of Physics and Technology

Email: taidakov@gmail.com
俄罗斯联邦, 53 Leninsky prosp., Moscow, 119991; 9 Institutskii per., Dolgoprudnyi, 141700

S. Nefedov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: taidakov@gmail.com
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991

I. Taidakov

P. N. Lebedev Physical Institute, Russian Academy of Sciences; Moscow Institute of Physics and Technology

编辑信件的主要联系方式.
Email: taidakov@gmail.com
俄罗斯联邦, 53 Leninsky prosp., Moscow, 119991; 9 Institutskii per., Dolgoprudnyi, 141700

补充文件

附件文件
动作
1. JATS XML

版权所有 © Springer Science+Business Media New York, 2016