Email this article Synthesis of cyclic acetals of acetylenic carbonyl compounds
- Authors: Golovanov A.A.1, Raskil’dina G.Z.2, Bekin V.V.1, Bunev A.S.1, Mikhailova N.N.1, Zlotskii S.S.2
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Affiliations:
- Togliatti State University
- Ufa State Petroleum Technological University
- Issue: Vol 65, No 7 (2016)
- Pages: 1757-1760
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238545
- DOI: https://doi.org/10.1007/s11172-016-1507-8
- ID: 238545
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Abstract
A condensation of α-acetylenic carbonyl compounds and their acyclic acetals with 1,2-diols gave substituted 1,3-dioxacycloalkanes in up to 90% yields. 2,4-Disubstituted 1,3-dioxolanes were formed as mixtures of steric isomers, in which trans-forms predominated according to the B3LYP/6-311+G(2d,p) calculations.
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About the authors
A. A. Golovanov
Togliatti State University
Email: graskildina444@mail.ru
Russian Federation, 14 ul. Belorusskaya, Togliatti, 445667
G. Z. Raskil’dina
Ufa State Petroleum Technological University
Author for correspondence.
Email: graskildina444@mail.ru
Russian Federation, 1 ul. Kosmonavtov, Ufa, 450000
V. V. Bekin
Togliatti State University
Email: graskildina444@mail.ru
Russian Federation, 14 ul. Belorusskaya, Togliatti, 445667
A. S. Bunev
Togliatti State University
Email: graskildina444@mail.ru
Russian Federation, 14 ul. Belorusskaya, Togliatti, 445667
N. N. Mikhailova
Togliatti State University
Email: graskildina444@mail.ru
Russian Federation, 14 ul. Belorusskaya, Togliatti, 445667
S. S. Zlotskii
Ufa State Petroleum Technological University
Email: graskildina444@mail.ru
Russian Federation, 1 ul. Kosmonavtov, Ufa, 450000
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