Email this article Specifics of luminescence of (benzoxazolyl)phenolate and (benzothiazolyl)naphtholate heterometallic Zn, Sc, Nd, Sm, Er, and Yb complexes
- Authors: Balashova T.V.1, Pushkarev A.P.1, Il’ichev V.A.1, Grishin I.D.2, Govorova D.V.1,2, Bochkarev M.N.1
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Affiliations:
- G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
- N. I. Lobachevsky State University of Nizhny Novgorod
- Issue: Vol 65, No 7 (2016)
- Pages: 1739-1742
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238532
- DOI: https://doi.org/10.1007/s11172-016-1504-y
- ID: 238532
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Abstract
Heterometallic complexes Ln(L1)5Zn (Ln = Sc, Sm, Gd) were obtained by the reactions of silylamides Ln[N(SiMe)2]3 with 2-(benzoxazol-2-yl)phenol (HL1) in the presence of diethylzinc. Similar reactions with 3-(benzothiazol-2-yl)-2-naphthol (HL2) led to the formation of complexes Ln(L2)5Zn (Ln = Nd, Er, Gd, Yb). The introduction of the zinc-containing fragments provided a considerable increase of photo- and electroluminescence intensity of the scandium complex.
About the authors
T. V. Balashova
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: petrovsk@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950
A. P. Pushkarev
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: petrovsk@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950
V. A. Il’ichev
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: petrovsk@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950
I. D. Grishin
N. I. Lobachevsky State University of Nizhny Novgorod
Email: petrovsk@iomc.ras.ru
Russian Federation, 23/2 prosp. Gagarina, Nizhny Novgorod, 603950
D. V. Govorova
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences; N. I. Lobachevsky State University of Nizhny Novgorod
Email: petrovsk@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950; 23/2 prosp. Gagarina, Nizhny Novgorod, 603950
M. N. Bochkarev
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: petrovsk@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950
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