Email this article Synthesis and oxidation of sulfides based on (–)-caryophyllene oxide and tert-butanethiol
- Authors: Gyrdymova J.W.1, Izmest´ev E.S.1, Rubtsova S.A.1, Kutchin A.V.1
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Affiliations:
- Institute of Chemistry, Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences
- Issue: Vol 65, No 5 (2016)
- Pages: 1238-1242
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238078
- DOI: https://doi.org/10.1007/s11172-016-1441-9
- ID: 238078
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Abstract
An acid-catalyzed reaction of (–)-caryophyllene oxide with tert-butanethiol led to sulfides with the clovane structure of the sesquiterpene fragment in up to 63% yields. The oxidation of these sulfides gave sulfoxides in up to 38% yields (de 59%) and sulfones in up to 89%.
About the authors
J. W. Gyrdymova
Institute of Chemistry, Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences
Author for correspondence.
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, 48 ul. Pervomaiskaya, Syktyvkar, 167982
E. S. Izmest´ev
Institute of Chemistry, Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, 48 ul. Pervomaiskaya, Syktyvkar, 167982
S. A. Rubtsova
Institute of Chemistry, Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, 48 ul. Pervomaiskaya, Syktyvkar, 167982
A. V. Kutchin
Institute of Chemistry, Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, 48 ul. Pervomaiskaya, Syktyvkar, 167982
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