The study of epoxidation of allyl chloride in methanol in the presence of extruded titanium containing silicalite
- Authors: Sulimov A.V.1, Danov S.M.1, Ovcharova A.V.1, Ovcharov A.A.1, Flid V.R.2, Leont’eva S.V.2, Flid M.R.3, Trushechkina M.A.3
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Affiliations:
- R. E. Alekseev Nizhny Novgorod State Technical University
- M. V. Lomonosov Moscow State University of Fine Chemical Technology
- R&D Engineering Centre Syntez
- Issue: Vol 65, No 2 (2016)
- Pages: 469-472
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237161
- DOI: https://doi.org/10.1007/s11172-016-1323-1
- ID: 237161
Cite item
Abstract
The liquid-phase epoxidation of allyl chloride in methanol with aqueous solution of hydrogen peroxide was conducted in the presence of extruded titanium containing silicalite and the physico-chemical features of the process were investigated. The effect of the amount of solvent, the initial ratio of the allyl chloride to hydrogen peroxide and the temperature of the process on the yield of the target product (epichlorohydrin) and by-products (3-chloro-1,2-propanediol and 3-chloro-1-methoxypropanol-2) was studied. Based on the obtained results, the optimum conditions of synthesis of epichlorohydrin for a laboratory scale continuous setup were recommended.
About the authors
A. V. Sulimov
R. E. Alekseev Nizhny Novgorod State Technical University
Author for correspondence.
Email: epoxide@mail.ru
Russian Federation, 24 ul. Minina, Nizhny Novgorod, 603950
S. M. Danov
R. E. Alekseev Nizhny Novgorod State Technical University
Email: epoxide@mail.ru
Russian Federation, 24 ul. Minina, Nizhny Novgorod, 603950
A. V. Ovcharova
R. E. Alekseev Nizhny Novgorod State Technical University
Email: epoxide@mail.ru
Russian Federation, 24 ul. Minina, Nizhny Novgorod, 603950
A. A. Ovcharov
R. E. Alekseev Nizhny Novgorod State Technical University
Email: epoxide@mail.ru
Russian Federation, 24 ul. Minina, Nizhny Novgorod, 603950
V. R. Flid
M. V. Lomonosov Moscow State University of Fine Chemical Technology
Email: epoxide@mail.ru
Russian Federation, 86 prosp. Vernadskogo, Moscow, 119571
S. V. Leont’eva
M. V. Lomonosov Moscow State University of Fine Chemical Technology
Email: epoxide@mail.ru
Russian Federation, 86 prosp. Vernadskogo, Moscow, 119571
M. R. Flid
R&D Engineering Centre Syntez
Email: epoxide@mail.ru
Russian Federation, 86 prosp. Vernadskogo, Moscow, 119571
M. A. Trushechkina
R&D Engineering Centre Syntez
Email: epoxide@mail.ru
Russian Federation, 86 prosp. Vernadskogo, Moscow, 119571