Oxidative nucleophilic substitution reaction of alkyl iodides upon treatment with perchlorate and dinitramide anions. Synthesis of alkyl-substituted perchlorates
- Authors: Yashin N.V.1,2, Averina E.B.1,2,3, Grishin Y.K.1, Rybakov V.B.1, Kuznetsova T.S.1, Zefirov N.S.1,2,3
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Affiliations:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Institute of Physiologically Active Compounds, Russian Academy of Sciences
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Issue: Vol 65, No 2 (2016)
- Pages: 451-455
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237139
- DOI: https://doi.org/10.1007/s11172-016-1320-4
- ID: 237139
Cite item
Abstract
Reactions of oxidative nucleophilic substitution of alkyl iodides with lithium perchlorate and dinitramide were studied. The reactions of alkyl iodides and lithium perchlorate, proceeding in the presence of nitronium tetrafluoroborate as an oxidant, furnished a series of new alkyl perchlorates, including those containing an adamantyl fragment. Spectral properties of alkyl perchlorates were studied in detail for the first time. The reactions of oxidative nucleophilic substitution of iodoacetic ester and lithium dinitramide, proceeding upon treatment with nitronium tetrafluoroborate or ozone, resulted in the substitution of an iodine atom with the nitrate anion.
About the authors
N. V. Yashin
Department of Chemistry, M. V. Lomonosov Moscow State University; Institute of Physiologically Active Compounds, Russian Academy of Sciences
Email: elaver@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991; 1 Severnyi pr-d, Chernogolovka, Moscow Region, 142432
E. B. Averina
Department of Chemistry, M. V. Lomonosov Moscow State University; Institute of Physiologically Active Compounds, Russian Academy of Sciences; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: elaver@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991; 1 Severnyi pr-d, Chernogolovka, Moscow Region, 142432; 47 Leninsky prosp., Moscow, 119991
Yu. K. Grishin
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: elaver@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
V. B. Rybakov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: elaver@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
T. S. Kuznetsova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: elaver@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
N. S. Zefirov
Department of Chemistry, M. V. Lomonosov Moscow State University; Institute of Physiologically Active Compounds, Russian Academy of Sciences; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: elaver@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991; 1 Severnyi pr-d, Chernogolovka, Moscow Region, 142432; 47 Leninsky prosp., Moscow, 119991