Synthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles

M. B. Gazizov; S. Yu. Ivanova; R. F. Karimova; L. R. Bagauva; K. S. Gazizova; A. A. Karimova

doi:10.1007/s11172-016-1282-6

Synthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles

Authors: Gazizov M.B.¹, Ivanova S.Y.¹, Karimova R.F.¹, Bagauva L.R.¹, Gazizova K.S.¹, Karimova A.A.¹
Affiliations:
1. Kazan National Research Technological University
Issue: Vol 65, No 1 (2016)
Pages: 191-194
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/236886
DOI: https://doi.org/10.1007/s11172-016-1282-6
ID: 236886

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Abstract

4-(Dibromomethyl)benzenecarbaldehyde was first synthesized and its preparation method jointly with terephthalic aldehyde was developed. Its reactions with O- and N-nucleophiles were studied: the reaction of this aldehyde with trialkyl orthoformates results in the formation of acetals while reacting with primary amines it forms imines, including those containing an additional acetal group.