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Gas-Phase Conversion of Uranium Monocarbide in a Nitrating Atmosphere


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Resumo

Gas-phase conversion of UC in NOx-air, NOx-H20 (vapor)-air, and HN03 (vapor)-air atmospheres in the temperature interval from 298 to 673 K was studied. In the course of the gas-phase conversion in an NOx-air atmosphere, UC transforms into uranium oxides and oxyhydroxides; uranyl nitrates and hydroxyni-trates are formed in smaller amounts. In NOx-H20 (vapor)-air and HN03 (vapor)-air atmospheres, the major conversion products are uranyl nitrate hydrates, with the nitration occurring at a lower temperature than in an NOx-air atmosphere.

Sobre autores

S. Kulyukhin

Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: kulyukhin@ipc.rssi.ru
Rússia, Leninskii pr. 31, korp. 4, Moscow, 119071

Yu. Nevolin

Radiochemistry Chair, Chemical Department

Email: kulyukhin@ipc.rssi.ru
Rússia, Moscow, 119991

A. Gordeev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: kulyukhin@ipc.rssi.ru
Rússia, Leninskii pr. 31, korp. 4, Moscow, 119071

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