Change in the mechanism of conductivity in ZrO2-based crystals depending on the content of stabilizing Y2O3 additive


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Abstract

The interrelationship between the structure, phase composition, and transport characteristics of solid electrolytes based on ZrO2 has been studied as dependent on the content of stabilizing Y2O3 additive. It is established that twin boundaries do not lead to the appearance of additional mechanism of ionic conductivity acceleration in ZrO2–Y2O3 crystals. The maximum conductivity has been observed in ZrO2–(8–10) mol % Y2O3 crystals containing a t” phase, in which oxygen atoms are displaced from high-symmetry positions characteristic of the cubic phase.

About the authors

M. A. Borik

Prokhorov General Physics Institute

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991

S. I. Bredikhin

Institute of Solid State Physics

Email: ntabachkova@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432

V. T. Bublik

National University of Science and Technology Moscow Institute of Steel and Alloys

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991

A. V. Kulebyakin

Prokhorov General Physics Institute

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991

I. E. Kuritsyna

Institute of Solid State Physics

Email: ntabachkova@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432

E. E. Lomonova

Prokhorov General Physics Institute

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991

F. O. Milovich

National University of Science and Technology Moscow Institute of Steel and Alloys

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991

V. A. Myzina

Prokhorov General Physics Institute

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991

V. V. Osiko

Prokhorov General Physics Institute

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991

S. V. Seryakov

Prokhorov General Physics Institute; National University of Science and Technology Moscow Institute of Steel and Alloys

Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991; Moscow, 119991

N. Yu. Tabachkova

National University of Science and Technology Moscow Institute of Steel and Alloys

Author for correspondence.
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991


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