Change in the mechanism of conductivity in ZrO2-based crystals depending on the content of stabilizing Y2O3 additive
- Authors: Borik M.A.1, Bredikhin S.I.2, Bublik V.T.3, Kulebyakin A.V.1, Kuritsyna I.E.2, Lomonova E.E.1, Milovich F.O.3, Myzina V.A.1, Osiko V.V.1, Seryakov S.V.1,3, Tabachkova N.Y.3
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Affiliations:
- Prokhorov General Physics Institute
- Institute of Solid State Physics
- National University of Science and Technology Moscow Institute of Steel and Alloys
- Issue: Vol 43, No 3 (2017)
- Pages: 289-292
- Section: Article
- URL: https://journals.rcsi.science/1063-7850/article/view/203923
- DOI: https://doi.org/10.1134/S1063785017030166
- ID: 203923
Cite item
Abstract
The interrelationship between the structure, phase composition, and transport characteristics of solid electrolytes based on ZrO2 has been studied as dependent on the content of stabilizing Y2O3 additive. It is established that twin boundaries do not lead to the appearance of additional mechanism of ionic conductivity acceleration in ZrO2–Y2O3 crystals. The maximum conductivity has been observed in ZrO2–(8–10) mol % Y2O3 crystals containing a t” phase, in which oxygen atoms are displaced from high-symmetry positions characteristic of the cubic phase.
About the authors
M. A. Borik
Prokhorov General Physics Institute
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991
S. I. Bredikhin
Institute of Solid State Physics
Email: ntabachkova@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. T. Bublik
National University of Science and Technology Moscow Institute of Steel and Alloys
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991
A. V. Kulebyakin
Prokhorov General Physics Institute
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991
I. E. Kuritsyna
Institute of Solid State Physics
Email: ntabachkova@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432
E. E. Lomonova
Prokhorov General Physics Institute
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991
F. O. Milovich
National University of Science and Technology Moscow Institute of Steel and Alloys
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991
V. A. Myzina
Prokhorov General Physics Institute
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991
V. V. Osiko
Prokhorov General Physics Institute
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991
S. V. Seryakov
Prokhorov General Physics Institute; National University of Science and Technology Moscow Institute of Steel and Alloys
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991; Moscow, 119991
N. Yu. Tabachkova
National University of Science and Technology Moscow Institute of Steel and Alloys
Author for correspondence.
Email: ntabachkova@gmail.com
Russian Federation, Moscow, 119991