Change in the mechanism of conductivity in ZrO2-based crystals depending on the content of stabilizing Y2O3 additive

Resumo

The interrelationship between the structure, phase composition, and transport characteristics of solid electrolytes based on ZrO₂ has been studied as dependent on the content of stabilizing Y₂O₃ additive. It is established that twin boundaries do not lead to the appearance of additional mechanism of ionic conductivity acceleration in ZrO₂–Y₂O₃ crystals. The maximum conductivity has been observed in ZrO₂–(8–10) mol % Y₂O₃ crystals containing a t” phase, in which oxygen atoms are displaced from high-symmetry positions characteristic of the cubic phase.