Low-Gas Detonation in Low-Density Mechanically Activated Powder Mixtures


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Abstract

We have analyzed experimental data on supersonic self-sustained propagation of an energy-release wave in low-density mechanically activated mixtures. Various mechanisms that can be responsible for this process have been investigated, and the mechanism for detonation-like propagation of reaction in powder mixtures has been proposed. It is shown that under certain conditions, this process possesses all features of detonation and must be treated as a variety of detonation. It is demonstrated that this type of detonation basically differs from classical “ideal” detonation: instead of a shock wave, a compaction wave propagates in a powder mixture, in which powder compaction and not compression of particle material occurs due to mutual displacement of particles. In this case, a chemical reaction is initiated due to mutual friction of oxidizer and fuel particles in the powder compaction wave.

About the authors

S. A. Rashkovskiy

Ishlinsky Institute of Problems of Mechanics, Russian Academy of Sciences; Semenov Institute of Chemical Physics, Russian Academy of Sciences

Author for correspondence.
Email: rash@ipmnet.ru
Russian Federation, Moscow, 119526; Moscow, 119991

A. Yu. Dolgoborodov

Joint Institute for High Temperatures, Russian Academy of Sciences; Semenov Institute of Chemical Physics, Russian Academy of Sciences; National Research Nuclear University MEPhI (Moscow Engineering Physics Institute)

Email: rash@ipmnet.ru
Russian Federation, Moscow, 125412; Moscow, 119991; Moscow, 115409


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