Generation and Fragmentation of Phthalide Derivative Negative Ions
- Authors: Asfandiarov N.L.1, Pshenichnyuk S.A.1, Rakhmeev R.G.1,2, Lachinov A.N.1, Kraikin V.A.3
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Affiliations:
- Institute of Physics of Molecules and Crystals, Ufa Federal Research Center
- Eastern Academy of Economics, Law, and Humanities
- Ufa Institute of Chemistry
- Issue: Vol 63, No 7 (2018)
- Pages: 1054-1059
- Section: Electrophysics, Electron and Ion Beams, Physics of Accelerators
- URL: https://journals.rcsi.science/1063-7842/article/view/201725
- DOI: https://doi.org/10.1134/S1063784218070034
- ID: 201725
Cite item
Abstract
Molecules of diphenylphthalide and 3,3-diphenylphthalide-4′,4′-dicarbonic acid have been studied using the method of dissociative electron capture negative ion mass spectrometry. The mean lifetimes of negative molecular ions relative to the electron detachment have been measured. The electron affinity has been estimated in the Arrhenius approximation and calculated by the DFT B3LYP/6-31G+(d) method.
About the authors
N. L. Asfandiarov
Institute of Physics of Molecules and Crystals, Ufa Federal Research Center
Author for correspondence.
Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075
S. A. Pshenichnyuk
Institute of Physics of Molecules and Crystals, Ufa Federal Research Center
Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075
R. G. Rakhmeev
Institute of Physics of Molecules and Crystals, Ufa Federal Research Center; Eastern Academy of Economics, Law, and Humanities
Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075; Ufa, Republic of Bashkortostan, 450071
A. N. Lachinov
Institute of Physics of Molecules and Crystals, Ufa Federal Research Center
Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075
V. A. Kraikin
Ufa Institute of Chemistry
Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450054