Generation and Fragmentation of Phthalide Derivative Negative Ions


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Abstract

Molecules of diphenylphthalide and 3,3-diphenylphthalide-4′,4′-dicarbonic acid have been studied using the method of dissociative electron capture negative ion mass spectrometry. The mean lifetimes of negative molecular ions relative to the electron detachment have been measured. The electron affinity has been estimated in the Arrhenius approximation and calculated by the DFT B3LYP/6-31G+(d) method.

About the authors

N. L. Asfandiarov

Institute of Physics of Molecules and Crystals, Ufa Federal Research Center

Author for correspondence.
Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075

S. A. Pshenichnyuk

Institute of Physics of Molecules and Crystals, Ufa Federal Research Center

Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075

R. G. Rakhmeev

Institute of Physics of Molecules and Crystals, Ufa Federal Research Center; Eastern Academy of Economics, Law, and Humanities

Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075; Ufa, Republic of Bashkortostan, 450071

A. N. Lachinov

Institute of Physics of Molecules and Crystals, Ufa Federal Research Center

Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450075

V. A. Kraikin

Ufa Institute of Chemistry

Email: nail@anrb.ru
Russian Federation, Ufa, Republic of Bashkortostan, 450054


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