High-Temperature Heat Capacity of Pb10 – xNdx(GeO4)2 + x(VO4)4 – x (x = 0–3) Apatites
- Autores: Denisova L.T.1, Golubeva E.O.1, Belousova N.V.1, Denisov V.M.1, Galiakhmetova N.A.1
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Afiliações:
- Institute of Non-Ferrous Metals and Material Science, Siberian Federal University
- Edição: Volume 61, Nº 7 (2019)
- Páginas: 1343-1346
- Seção: Thermal Properties
- URL: https://journals.rcsi.science/1063-7834/article/view/205975
- DOI: https://doi.org/10.1134/S1063783419070060
- ID: 205975
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Resumo
We obtained Pb10 – xNdx(GeO4)2 + x(VO4)4 – x (x = 0–3) compounds with an apatite structure by solid-phase synthesis from initial oxides PbO, Nd2O3, GeO2, and V2O5 with successive annealing at 773–1073 K in the air. Their high-temperature heat capacity was measured by differential scanning calorimetry. The thermodynamic functions (changes in enthalpy, entropy, and reduced Gibbs energy) are calculated using the experimental dependences of Cp = f(T).
Sobre autores
L. Denisova
Institute of Non-Ferrous Metals and Material Science, Siberian Federal University
Autor responsável pela correspondência
Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025
E. Golubeva
Institute of Non-Ferrous Metals and Material Science, Siberian Federal University
Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025
N. Belousova
Institute of Non-Ferrous Metals and Material Science, Siberian Federal University
Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025
V. Denisov
Institute of Non-Ferrous Metals and Material Science, Siberian Federal University
Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025
N. Galiakhmetova
Institute of Non-Ferrous Metals and Material Science, Siberian Federal University
Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660025
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