High-Temperature Heat Capacity of Pb10 – xNdx(GeO4)2 + x(VO4)4 – x (x = 0–3) Apatites


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We obtained Pb10 – xNdx(GeO4)2 + x(VO4)4 – x (x = 0–3) compounds with an apatite structure by solid-phase synthesis from initial oxides PbO, Nd2O3, GeO2, and V2O5 with successive annealing at 773–1073 K in the air. Their high-temperature heat capacity was measured by differential scanning calorimetry. The thermodynamic functions (changes in enthalpy, entropy, and reduced Gibbs energy) are calculated using the experimental dependences of Cp = f(T).

作者简介

L. Denisova

Institute of Non-Ferrous Metals and Material Science, Siberian Federal University

编辑信件的主要联系方式.
Email: antluba@mail.ru
俄罗斯联邦, Krasnoyarsk, 660025

E. Golubeva

Institute of Non-Ferrous Metals and Material Science, Siberian Federal University

Email: antluba@mail.ru
俄罗斯联邦, Krasnoyarsk, 660025

N. Belousova

Institute of Non-Ferrous Metals and Material Science, Siberian Federal University

Email: antluba@mail.ru
俄罗斯联邦, Krasnoyarsk, 660025

V. Denisov

Institute of Non-Ferrous Metals and Material Science, Siberian Federal University

Email: antluba@mail.ru
俄罗斯联邦, Krasnoyarsk, 660025

N. Galiakhmetova

Institute of Non-Ferrous Metals and Material Science, Siberian Federal University

Email: antluba@mail.ru
俄罗斯联邦, Krasnoyarsk, 660025

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