Email this article Correlation of the properties of ionic conductivity–structure for the RbGaO2 solid electrolyte
- Authors: Proskurnina N.V.1, Voronin V.I.1, Berger I.F.2, Shekhtman G.S.3
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Affiliations:
- Institute of Metal Physics, Ural Branch
- Institute of Solid State Chemistry, Ural Branch
- Institute of High Temperature Electrochemistry, Ural Branch
- Issue: Vol 58, No 12 (2016)
- Pages: 2523-2528
- Section: Phase Transitions
- URL: https://journals.rcsi.science/1063-7834/article/view/199376
- DOI: https://doi.org/10.1134/S1063783416120246
- ID: 199376
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Abstract
The crystal structure of rubidium gallate RbGaO2 in the temperature range of 300–853 K has been investigated using high-temperature neutron diffraction. The channels available for the motion of rubidium cations in the low-temperature and high-temperature modifications of RbGaO2 have been determined using the computer simulation with the TOPOS program. A correlation between the radius of the migration channel cross section and the rubidium cation conductivity has been established.
About the authors
N. V. Proskurnina
Institute of Metal Physics, Ural Branch
Author for correspondence.
Email: Proskurnina@imp.uran.ru
Russian Federation, ul. Sofii Kovalevskoi 18, Yekaterinburg, 620990
V. I. Voronin
Institute of Metal Physics, Ural Branch
Email: Proskurnina@imp.uran.ru
Russian Federation, ul. Sofii Kovalevskoi 18, Yekaterinburg, 620990
I. F. Berger
Institute of Solid State Chemistry, Ural Branch
Email: Proskurnina@imp.uran.ru
Russian Federation, ul. Pervomaiskaya 91, Yekaterinburg, 620990
G. Sh. Shekhtman
Institute of High Temperature Electrochemistry, Ural Branch
Email: Proskurnina@imp.uran.ru
Russian Federation, ul. Akademicheskaya 20, Yekaterinburg, 620990
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