On the Crystallographic Polytypes SrAl12O19 (BaFe12O19)–BaFe18O27


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A crystallographic analysis of SrAl12O19 (isostructural to BaFe12O19) and BaFe18O27 showed that the structures of both polytypes contain almost identical cationic and anionic (with participation of a large cation) sublattices, whose geometry is consistent with the high symmetry P63/mmc of these compounds. The presence of unified “skeletal” sublattices is considered to be the main condition for the formation of polytype structures.

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S. Borisov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

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Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

S. Magarill

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

N. Pervukhina

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

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