Hydrothermal Synthesis, Crystal Structure, and Photoluminescent Properties of Li[UO2(CH3COO)3]3[Co(H2O)6]


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Аннотация

Single crystal of Li[UO2(CH3COO)3]3[Co(H2O)6] was prepared and found to crystallize in the monoclinic crystal system in the sp. gr. C2/c, with Z = 2, and unit cell parameters a = 22.1857(15) Å, b = 13.6477(8) Å, c = 15.6921(10) Å, β = 117.842(9)°, V = 4201.3(4) Å3. The crystal was characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and differential scanning calorimetry. The single crystal X-ray diffraction analysis revealed that the crystal has a lamellar structure in which a cobalt hydrate is sandwiched within the Li[UO2(CH3COO)3]32- chains. Furthermore, the room temperature photoluminescence spectrum of the complex was investigated in the solid state.

Авторлар туралы

Murad AlDamen

School of Science

Хат алмасуға жауапты Автор.
Email: maldamen@ju.edu.jo
Иордания, Amman, 11942

Hassan Juwhari

School of Science

Email: maldamen@ju.edu.jo
Иордания, Amman, 11942

Aya Al-zuheiri

School of Science

Email: maldamen@ju.edu.jo
Иордания, Amman, 11942

Louy Alnazer

School of Science

Email: maldamen@ju.edu.jo
Иордания, Amman, 11942

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