Synthesis and structure of a 2D Zn complex with mixed ligands stacked in offset ABAB manner


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Resumo

The title complex, {[Zn(ODIB)1/2(bpdc)]·2DMF}n was prepared under hydrothermal conditions (dimethylformamide and water) based on two ligands, namely, 1,1′-oxy-bis[3,5-diimidazolyl-benzene] (ODIB) and biphenyldicarboxylic acid (H2bpdc). ODIB ligands link Zn cations to give layers in crystal. bpdc2– anions coordinate to Zn atoms, however, their introduction does not increase the dimension of the structure. Each layer is partially passes through the adjacent layers in the offset ABAB manner.

Sobre autores

Ling Qin

Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering

Autor responsável pela correspondência
Email: qinling0924013@163.com
República Popular da China, Xuancheng, Anhui, 242000; Nanjing

Yan-Qing Wang

Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering

Email: qinling0924013@163.com
República Popular da China, Xuancheng, Anhui, 242000; Nanjing

Gang Ni

Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering

Email: qinling0924013@163.com
República Popular da China, Xuancheng, Anhui, 242000; Nanjing

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