Synthesis and structure of a 2D Zn complex with mixed ligands stacked in offset ABAB manner


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详细

The title complex, {[Zn(ODIB)1/2(bpdc)]·2DMF}n was prepared under hydrothermal conditions (dimethylformamide and water) based on two ligands, namely, 1,1′-oxy-bis[3,5-diimidazolyl-benzene] (ODIB) and biphenyldicarboxylic acid (H2bpdc). ODIB ligands link Zn cations to give layers in crystal. bpdc2– anions coordinate to Zn atoms, however, their introduction does not increase the dimension of the structure. Each layer is partially passes through the adjacent layers in the offset ABAB manner.

作者简介

Ling Qin

Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering

编辑信件的主要联系方式.
Email: qinling0924013@163.com
中国, Xuancheng, Anhui, 242000; Nanjing

Yan-Qing Wang

Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering

Email: qinling0924013@163.com
中国, Xuancheng, Anhui, 242000; Nanjing

Gang Ni

Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering

Email: qinling0924013@163.com
中国, Xuancheng, Anhui, 242000; Nanjing

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