Synthesis and crystal structure of a new 2,6-dimethyl piperazine-1,4-diium perchlorate monohydrate: [C6H16N2](ClO4)2 · H2O
- Авторы: Mleh C.1, Roisnel T.2, Marouani H.1
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Учреждения:
- Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte
- Centre de Diffractométrie X, UMR 6226 CNRS, Unité Sciences Chimiques de Rennes
- Выпуск: Том 62, № 2 (2017)
- Страницы: 246-248
- Раздел: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/190783
- DOI: https://doi.org/10.1134/S1063774517020171
- ID: 190783
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Аннотация
A proton transfer compound 2,6-dimethyl piperazine-1,4-diium perchlorate monohydrate was synthesized by slow evaporation at room temperature using 2,6-dimethyl piperazine as template. The asymmetric unit contains one organic dication, two crystal graphically independent perchlorate anions and one water molecule. Each organic entities is engaged in a large number of bifurcated and non-bifurcated N–H···O (O) and C–H···O hydrogen bonds with different species and enhanced the three dimensional supramolecular network. In addition, the diprotonated piperazine ring adopts a chair conformation with the methyl groups occupying equatorial positions.
Об авторах
C. Mleh
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte
Email: houda.marouani@fsb.rnu.tn
Тунис, Zarzouna, Bizerte, 7021
T. Roisnel
Centre de Diffractométrie X, UMR 6226 CNRS, Unité Sciences Chimiques de Rennes
Email: houda.marouani@fsb.rnu.tn
Франция, 263 Avenue du Général Leclerc, Rennes, 35042
H. Marouani
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte
Автор, ответственный за переписку.
Email: houda.marouani@fsb.rnu.tn
Тунис, Zarzouna, Bizerte, 7021