Synthesis and crystal structure of a new 2,6-dimethyl piperazine-1,4-diium perchlorate monohydrate: [C6H16N2](ClO4)2 · H2O
- Authors: Mleh C.B.1, Roisnel T.2, Marouani H.1
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Affiliations:
- Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte
- Centre de Diffractométrie X, UMR 6226 CNRS, Unité Sciences Chimiques de Rennes
- Issue: Vol 62, No 2 (2017)
- Pages: 246-248
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/190783
- DOI: https://doi.org/10.1134/S1063774517020171
- ID: 190783
Cite item
Abstract
A proton transfer compound 2,6-dimethyl piperazine-1,4-diium perchlorate monohydrate was synthesized by slow evaporation at room temperature using 2,6-dimethyl piperazine as template. The asymmetric unit contains one organic dication, two crystal graphically independent perchlorate anions and one water molecule. Each organic entities is engaged in a large number of bifurcated and non-bifurcated N–H···O (O) and C–H···O hydrogen bonds with different species and enhanced the three dimensional supramolecular network. In addition, the diprotonated piperazine ring adopts a chair conformation with the methyl groups occupying equatorial positions.
About the authors
C. Ben Mleh
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte
Email: houda.marouani@fsb.rnu.tn
Tunisia, Zarzouna, Bizerte, 7021
T. Roisnel
Centre de Diffractométrie X, UMR 6226 CNRS, Unité Sciences Chimiques de Rennes
Email: houda.marouani@fsb.rnu.tn
France, 263 Avenue du Général Leclerc, Rennes, 35042
H. Marouani
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte
Author for correspondence.
Email: houda.marouani@fsb.rnu.tn
Tunisia, Zarzouna, Bizerte, 7021