Three Cu(II) Complexes Constructed by Flexible bis-Imidazole and Different Anions: From 0D Architecture to 2D Layer
- Autores: Lu J.F.1, Yu X.H.1, Zhao C.B.1, Zheng N.1, Yue S.Y.1, Li L.1, Tang Z.H.1, Ge H.G.1, Jin L.X.1
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Afiliações:
- Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
- Edição: Volume 64, Nº 7 (2019)
- Páginas: 1055-1061
- Seção: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194414
- DOI: https://doi.org/10.1134/S1063774519070095
- ID: 194414
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Resumo
Three new Cu(II) complexes, Cu(1,3-bip)(Ac)2 (I), {[Cu(H2O)2(1,3-bip)2] · (NO3)2}n (II), {[Cu(1,3-bip)(1,4-bdc)]2 · H2O · MeOH}n (III), where 1,3-bip is 1,3-bis(imidazole)propane and 1,4-bdc is terephthalic acid, have been synthesized and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that the complex I shows a zero-dimensional architecture, the complex II shows a one-dimensional loop-like chain, and the complex III shows a two-dimensional (4,4) grid layer structure. In addition, the thermal stability of complexes was investigated.
Sobre autores
J. Lu
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
X. Yu
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
C. Zhao
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
N. Zheng
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
S. Yue
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
L. Li
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
Z. Tang
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
H. Ge
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Autor responsável pela correspondência
Email: gehg@snut.edu.cn
República Popular da China, Hanzhong, 723001
L. Jin
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Autor responsável pela correspondência
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001
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