Three Cu(II) Complexes Constructed by Flexible bis-Imidazole and Different Anions: From 0D Architecture to 2D Layer


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Resumo

Three new Cu(II) complexes, Cu(1,3-bip)(Ac)2 (I), {[Cu(H2O)2(1,3-bip)2] · (NO3)2}n (II), {[Cu(1,3-bip)(1,4-bdc)]2 · H2O · MeOH}n (III), where 1,3-bip is 1,3-bis(imidazole)propane and 1,4-bdc is terephthalic acid, have been synthesized and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that the complex I shows a zero-dimensional architecture, the complex II shows a one-dimensional loop-like chain, and the complex III shows a two-dimensional (4,4) grid layer structure. In addition, the thermal stability of complexes was investigated.

Sobre autores

J. Lu

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

X. Yu

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

C. Zhao

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

N. Zheng

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

S. Yue

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

L. Li

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

Z. Tang

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

H. Ge

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Autor responsável pela correspondência
Email: gehg@snut.edu.cn
República Popular da China, Hanzhong, 723001

L. Jin

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology

Autor responsável pela correspondência
Email: jinlx@snut.edu.cn
República Popular da China, Hanzhong, 723001

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