Email this article Three Cu(II) Complexes Constructed by Flexible bis-Imidazole and Different Anions: From 0D Architecture to 2D Layer
- Authors: Lu J.F.1, Yu X.H.1, Zhao C.B.1, Zheng N.1, Yue S.Y.1, Li L.1, Tang Z.H.1, Ge H.G.1, Jin L.X.1
-
Affiliations:
- Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
- Issue: Vol 64, No 7 (2019)
- Pages: 1055-1061
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194414
- DOI: https://doi.org/10.1134/S1063774519070095
- ID: 194414
Cite item
Open Access
Access granted
Subscription Access
Abstract
Three new Cu(II) complexes, Cu(1,3-bip)(Ac)2 (I), {[Cu(H2O)2(1,3-bip)2] · (NO3)2}n (II), {[Cu(1,3-bip)(1,4-bdc)]2 · H2O · MeOH}n (III), where 1,3-bip is 1,3-bis(imidazole)propane and 1,4-bdc is terephthalic acid, have been synthesized and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that the complex I shows a zero-dimensional architecture, the complex II shows a one-dimensional loop-like chain, and the complex III shows a two-dimensional (4,4) grid layer structure. In addition, the thermal stability of complexes was investigated.
About the authors
J. F. Lu
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
X. H. Yu
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
C. B. Zhao
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
N. Zheng
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
S. Y. Yue
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
L. Li
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
Z. H. Tang
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
H. G. Ge
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Author for correspondence.
Email: gehg@snut.edu.cn
China, Hanzhong, 723001
L. X. Jin
Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology
Author for correspondence.
Email: jinlx@snut.edu.cn
China, Hanzhong, 723001
Supplementary files
