The Growth and Properties of Guanylurea Hydrogen Phosphite Crystal


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Resumo

Aqueous solutions of guanylurea hydrogen phosphite (GUHP) have been synthesized. The temperature dependence of equilibrium GUHP concentration in water was obtained. The change in the density of aqueous GUHP solutions with a change in their concentration was investigated. The influence of the solution pH on the GUHP solubility in water in the temperature range of +25–45°C was analyzed. The crystallization range of monoclinic GUHP crystals, belonging to the sp. gr. Cc, was determined. GUHP crystals were grown using different methods, based on cooling or maintaining a constant temperature, with mixing aqueous solutions or without mixing. The properties of the grown crystals in the optical and THz ranges were investigated.

Sobre autores

A. Kaminskii

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119333

V. Manomenova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119333

E. Rudneva

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119333

N. Sorokina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119333

V. Grebenev

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119333

N. Kozlova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119333

A. Angeluts

Moscow State University

Email: labsol@yandex.ru
Rússia, Moscow, 119992

I. Ozheredov

Moscow State University; Institute of Laser and Information Technologies, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119992; Shatura, Moscow oblast, 140700

P. Solyankin

Moscow State University; Institute of Laser and Information Technologies, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119992; Shatura, Moscow oblast, 140700

I. Denisyuk

ITMO University

Email: labsol@yandex.ru
Rússia, St. Petersburg, 197101

M. Fokina

ITMO University

Email: labsol@yandex.ru
Rússia, St. Petersburg, 197101

N. Zulina

ITMO University

Email: labsol@yandex.ru
Rússia, St. Petersburg, 197101

A. Shkurinov

Moscow State University; Institute of Laser and Information Technologies, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: labsol@yandex.ru
Rússia, Moscow, 119992; Shatura, Moscow oblast, 140700

A. Voloshin

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Autor responsável pela correspondência
Email: labsol@yandex.ru
Rússia, Moscow, 119333

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