Synthesis and Crystal Structure of Di-μ-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-κN)aniline-κN]mercury(II)}
- Авторы: Khalaj M.1, Seftejani F.B.1, Ghazanfarpour-Darjani M.1, Lalegani A.1
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Учреждения:
- Young Researchers and Elite Club, Buinzahra Branch
- Выпуск: Том 62, № 7 (2017)
- Страницы: 1063-1065
- Раздел: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191660
- DOI: https://doi.org/10.1134/S1063774517070124
- ID: 191660
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Аннотация
The centrosymmetric dinuclear title complex [Hg2Cl4(dip)2] was synthesized using the Schiff base bidentate ligand (E)-4-ethyl-N-(pyridine-2-ylmethylene)benzeneamine (dip) and mercury(II) chloride salts. It has been characterized by elemental analysis, X-ray diffraction, and UV-Visible and infrared spectroscopic techniques. The X-ray analysis shows that the title compound crystallizes in the monoclinic sp. gr. P21/n, Z = 2 with a = 7.8233(17) Å, b = 15.178(3) Å, c = 12.559(3) Å, β = 97.021(3)°. The Hg(II) ion has a distorted trigonal–bipyramidal coordination environment formed by the bischelating N-heterocyclic ligands, two bridging Cl atoms and one terminal Cl atom.
Об авторах
M. Khalaj
Young Researchers and Elite Club, Buinzahra Branch
Автор, ответственный за переписку.
Email: khalaj_mehdi@yahoo.com
Иран, Buinzahra
F. Seftejani
Young Researchers and Elite Club, Buinzahra Branch
Email: khalaj_mehdi@yahoo.com
Иран, Buinzahra
M. Ghazanfarpour-Darjani
Young Researchers and Elite Club, Buinzahra Branch
Email: khalaj_mehdi@yahoo.com
Иран, Buinzahra
A. Lalegani
Young Researchers and Elite Club, Buinzahra Branch
Email: khalaj_mehdi@yahoo.com
Иран, Buinzahra
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