Synthesis, Structure, and Luminescent Properties of a Cadmium(II) Supramolecular Coordination Complex


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Аннотация

A new supramolecular complex [Cd(dcbpy)(im)2(H2O)2] · 3H2O (H2dcbpy = 4,4'-dicarboxy-2,2'-bipyridine, im = imidazole) has been prepared under hydrothermal conditions. Its crystal structure is determined with single crystal X-ray diffraction. Cd2+ atom is six-coordinated by one dcbpy ligand, two imidazole and two water molecules. Each [Cd(dcbpy)(im)2(H2O)2] unit is connected to neighboring units through intermolecular O–H···O hydrogen bonds to form a three-dimensional supramolecular network structure. A topology method has been used to simplify the network. The stability and luminescent properties of the complex obtained have been investigated.

Авторлар туралы

Y. Chen

Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University

Email: wanjuzhang@126.com
ҚХР, Huanggang, 438000

F. Peng

Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University

Email: wanjuzhang@126.com
ҚХР, Huanggang, 438000

Q. Zhang

Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University

Email: wanjuzhang@126.com
ҚХР, Huanggang, 438000

L. Huang

Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University

Email: wanjuzhang@126.com
ҚХР, Huanggang, 438000

W. Zhang

Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University

Хат алмасуға жауапты Автор.
Email: wanjuzhang@126.com
ҚХР, Huanggang, 438000

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