Email this article Synthesis, Structure, and Luminescent Properties of a Cadmium(II) Supramolecular Coordination Complex
- Authors: Chen Y.M.1, Peng F.1, Zhang Q.C.1, Huang L.C.1, Zhang W.J.1
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Affiliations:
- Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University
- Issue: Vol 64, No 7 (2019)
- Pages: 1094-1098
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194467
- DOI: https://doi.org/10.1134/S1063774519070046
- ID: 194467
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Abstract
A new supramolecular complex [Cd(dcbpy)(im)2(H2O)2] · 3H2O (H2dcbpy = 4,4'-dicarboxy-2,2'-bipyridine, im = imidazole) has been prepared under hydrothermal conditions. Its crystal structure is determined with single crystal X-ray diffraction. Cd2+ atom is six-coordinated by one dcbpy ligand, two imidazole and two water molecules. Each [Cd(dcbpy)(im)2(H2O)2] unit is connected to neighboring units through intermolecular O–H···O hydrogen bonds to form a three-dimensional supramolecular network structure. A topology method has been used to simplify the network. The stability and luminescent properties of the complex obtained have been investigated.
About the authors
Y. M. Chen
Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University
Email: wanjuzhang@126.com
China, Huanggang, 438000
F. Peng
Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University
Email: wanjuzhang@126.com
China, Huanggang, 438000
Q. C. Zhang
Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University
Email: wanjuzhang@126.com
China, Huanggang, 438000
L. C. Huang
Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University
Email: wanjuzhang@126.com
China, Huanggang, 438000
W. J. Zhang
Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University
Author for correspondence.
Email: wanjuzhang@126.com
China, Huanggang, 438000
