Specific Features of the Molecular and Crystalline Structure of Two Crystallosolvates of 4-Amino-N-(4-nitrophenyl)benzenelsulfonamide
- Authors: Tkachev V.V.1, Utenyshev A.N.1,2, Kazachenko V.P.3, Avramenko O.V.4
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Sechenov First Moscow State Medical University, Ministry of Health of the Russian Federation
- Institute of Physiologically Active Substances, Russian Academy of Sciences
- Peoples’ Friendship University of Russia (RUDN University)
- Issue: Vol 64, No 6 (2019)
- Pages: 894-897
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194298
- DOI: https://doi.org/10.1134/S1063774519060233
- ID: 194298
Cite item
Abstract
Two new crystallosolvates based on 4-amino-N-(4-nitrophenyl)benzenelsulfonamide with dimethyl sulfoxide and N,N-dimethylacetamide have been investigated by X-ray diffraction (XRD) analysis. It is shown that the solvent presence barely affects the molecular structure of the 4-amino-N-(4-nitrophenyl) benzenelsulfonamide compound, which was investigated previously (crystal without solvent), but affects its conformational structure. The intermolecular bond of the NH···O type (solvent molecules) is implemented in both new crystal structures
About the authors
V. V. Tkachev
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: uten@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
A. N. Utenyshev
Institute of Problems of Chemical Physics, Russian Academy of Sciences; Sechenov First Moscow State Medical University, Ministry of Health of the Russian Federation
Author for correspondence.
Email: uten@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
V. P. Kazachenko
Institute of Physiologically Active Substances, Russian Academy of Sciences
Email: uten@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
O. V. Avramenko
Peoples’ Friendship University of Russia (RUDN University)
Email: uten@icp.ac.ru
Russian Federation, Moscow, 117198