Specific Features of the Molecular and Crystalline Structure of Two Crystallosolvates of 4-Amino-N-(4-nitrophenyl)benzenelsulfonamide


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Abstract

Two new crystallosolvates based on 4-amino-N-(4-nitrophenyl)benzenelsulfonamide with dimethyl sulfoxide and N,N-dimethylacetamide have been investigated by X-ray diffraction (XRD) analysis. It is shown that the solvent presence barely affects the molecular structure of the 4-amino-N-(4-nitrophenyl) benzenelsulfonamide compound, which was investigated previously (crystal without solvent), but affects its conformational structure. The intermolecular bond of the NH···O type (solvent molecules) is implemented in both new crystal structures

About the authors

V. V. Tkachev

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: uten@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

A. N. Utenyshev

Institute of Problems of Chemical Physics, Russian Academy of Sciences; Sechenov First Moscow State Medical University, Ministry of Health of the Russian Federation

Author for correspondence.
Email: uten@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 119991

V. P. Kazachenko

Institute of Physiologically Active Substances, Russian Academy of Sciences

Email: uten@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

O. V. Avramenko

Peoples’ Friendship University of Russia (RUDN University)

Email: uten@icp.ac.ru
Russian Federation, Moscow, 117198


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