Skeletal Sublattices of Heavy Components As a Basis of Stability of Crystal Structures


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A crystallographic structural analysis of low- and high-temperature phases of BaSi2O5 and Na3SO4F compounds has been carried out in order to confirm the thesis that the stability of natural-abundant structural types is mainly determined by the configuration of the heaviest components. The geometry of cation (skeletal) sublattices is presented; it is shown that they play a key role in the formation of structures and are relatively stable at temperature phase transitions.

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S. Borisov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

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Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

S. Magarill

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

N. Pervukhina

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

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