Skeletal Sublattices of Heavy Components As a Basis of Stability of Crystal Structures
- 作者: Borisov S.V.1, Magarill S.A.1, Pervukhina N.V.1,2
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隶属关系:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- 期: 卷 64, 编号 1 (2019)
- 页面: 30-35
- 栏目: Theory of Crystal Structures
- URL: https://journals.rcsi.science/1063-7745/article/view/193559
- DOI: https://doi.org/10.1134/S1063774519010036
- ID: 193559
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详细
A crystallographic structural analysis of low- and high-temperature phases of BaSi2O5 and Na3SO4F compounds has been carried out in order to confirm the thesis that the stability of natural-abundant structural types is mainly determined by the configuration of the heaviest components. The geometry of cation (skeletal) sublattices is presented; it is shown that they play a key role in the formation of structures and are relatively stable at temperature phase transitions.
作者简介
S. Borisov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090
S. Magarill
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090
N. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: borisov@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090
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