Nanostructured Crystals of Fluorite Phases Sr1 – xRxF2 + x and Their Ordering: 12. Influence of Structural Ordering on the Fluorine-Ion Conductivity of Sr0.667R0.333F2.333 Alloys (R = Tb or Tm) at Their Annealing
- Authors: Sorokin N.I.1, Karimov D.N.1, Sul’yanova E.A.1, Sobolev B.P.1
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Affiliations:
- Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
- Issue: Vol 63, No 1 (2018)
- Pages: 121-126
- Section: Nanomaterials
- URL: https://journals.rcsi.science/1063-7745/article/view/192232
- DOI: https://doi.org/10.1134/S1063774518010182
- ID: 192232
Cite item
Abstract
The ionic conductivity of Sr0.667R0.333F2.333 alloys (rational Sr2RF7 compositions) in SrF2–RF3 systems (R = Tb or Tm), prepared by spontaneous crystallization, has been investigated for the “as-grown” state and after annealing in CF4 at 900 ± 20°C for 96 h. As-grown samples of both compositions, prepared by fast (200°C/min) melt crystallization, exhibit partial (nonequilibrium) ordering, which increases from Tb to Tm. Annealing of Sr0.667R0.333F2.333 alloys yields strong ordering (equilibrium for the annealing temperatures) of the fluorite structure (CaF2 type, sp. gr. Fm3̅m, Z = 4) at the formation of t-Sr2RF7 tetragonal compound (sp. gr. I4/m, Z = 30). It is established that ordering of the alloy fluorite structure reduces the fluorine-ion conductivity. After the annealing, the conductivity of Sr0.667R0.333F2.333 alloys with the initial (nonequilibrium) ordering stage of t-Sr2RF7 phases with almost complete (equilibrium) ordering decreases by a factor of 3–4.5.
About the authors
N. I. Sorokin
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Author for correspondence.
Email: nsorokin1@yandex.ru
Russian Federation, Moscow, 119333
D. N. Karimov
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Email: nsorokin1@yandex.ru
Russian Federation, Moscow, 119333
E. A. Sul’yanova
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Email: nsorokin1@yandex.ru
Russian Federation, Moscow, 119333
B. P. Sobolev
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Email: nsorokin1@yandex.ru
Russian Federation, Moscow, 119333