Ligands Entrapment in a 2D Parallel Stacked Co Complex with Mixed Ligands


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详细

The title complex, {[Co4(DPT)4(bdc)4] · DPT · DMF · H2O}n (1) was prepared under hydrothermal condition (dimethylformamide and water) based on mixed ligands, namely, 2,5-dipyridinethiophene (DPT) and 1,4-benzenedicarboxylate (H2bdc). DPT and bdc2– ligands link Co cations to give a 2D layer in the title complex. Each layer is stacked in parallel manners. The title compound has channels running in parallel to the a axis with the dimensions of 3.6 × 6.8 Å2, which entraps a guest DPT ligand molecule.

作者简介

Ling Qin

Department of Chemical Engineering and Food Processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering

编辑信件的主要联系方式.
Email: qinling0924013@163.com
中国, Xuancheng, Anhui, 242000; Nanjing, Jiangsu

Qing-He Liu

Department of Chemical Engineering and Food Processing, Xuancheng Campus

Email: qinling0924013@163.com
中国, Xuancheng, Anhui, 242000

Xi Yang

Department of Chemical Engineering and Food Processing, Xuancheng Campus

Email: qinling0924013@163.com
中国, Xuancheng, Anhui, 242000

Yan-Qing Wang

Department of Chemical Engineering and Food Processing, Xuancheng Campus

Email: qinling0924013@163.com
中国, Xuancheng, Anhui, 242000

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