Email this article A Novel Coordination Polymer Constructed by Hetero−Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa2(PDC)2(μ-H2O)(H2O)2]n
- Authors: Dou M.1, Lu J.1
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Affiliations:
- Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering
- Issue: Vol 62, No 7 (2017)
- Pages: 1055-1059
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191640
- DOI: https://doi.org/10.1134/S1063774517070197
- ID: 191640
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Abstract
A novel coordination polymer containing hetero-metal ions, [NiNa2(PDC)2(μ-H2O)(H2O)2]n, where PDC is 2,3-pyridine dicarboxylate ion, has been synthesized. In the structure, the PDC ligand chelates and bridges two Ni(II) and two Na(I) centers. Two kinds of metal centers are connected by μ4-PDC and μ2-H2O to form 2D coordination layers. Hydrogen bonds between coordination water molecules and carboxylate oxygen atoms further link these 2D coordination layers to form 3D supramolecular network.
About the authors
Ming-Yu Dou
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering
Email: lujinglcu@163.com
China, Liaocheng, 252059 P. R.
Jing Lu
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering
Author for correspondence.
Email: lujinglcu@163.com
China, Liaocheng, 252059 P. R.
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