电邮这篇文章 Synthesis, Structure, and Fluorescence of a Novel Cadmium Compound
- 作者: Yao Z.1, Chen W.2,3
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隶属关系:
- Biology and Chemistry Engineering Department
- Institute of Applied Chemistry, School of Chemistry and Chemical Engineering
- State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter
- 期: 卷 62, 编号 7 (2017)
- 页面: 1017-1021
- 栏目: Structure of Inorganic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191600
- DOI: https://doi.org/10.1134/S1063774517070355
- ID: 191600
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详细
A novel cadmium compound, [(CdI3)2(μ2-I)]2(Me2-4,4'-H2bipy)3 (1) (Me = methyl; 4,4'-bipy = 4,4'-bipyridine) with the Me2-4,4'-H2bipy moiety generated in situ, has been prepared through a solvothermal reaction and structurally characterized by X-ray single crystal diffraction analysis. Compound 1 is characterized by an isolated structural motif, consisting of [(CdI3)2(μ2-I)]3– anions and Me2-4,4'-H2bipy2+ cations. The [(CdI3)2(μ2-I)]3– anions and Me2-4,4'-H2bipy2+ cations interconnect together via C–H···I hydrogen-bonding interactions to complete a three-dimensional (3D) supramolecular network. Solid state fluorescent spectrum reveals an emission band in the violet region.
作者简介
Zhong-Liang Yao
Biology and Chemistry Engineering Department
Email: wtchen@jgsu.edu.cn
中国, Fuqing, Fujian, 350300
Wen-Tong Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter
编辑信件的主要联系方式.
Email: wtchen@jgsu.edu.cn
中国, Ji’an, Jiangxi, 343009; Fuzhou, Fujian, 350002
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