Email this article A luminescent 2D → 3D Cd complex via π-π* interaction based on bis(4-(1H-imidazol-1-yl)phenyl)amine and 1,3-dicarboxybenzene acid
- Authors: Zhang M.1, Zheng B.2, Liu X.1, Huang C.1,3, Wang B.2
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Affiliations:
- Department of Chemistry, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering
- Institute of Chemical Materials
- School of Chemistry and Life Science
- Issue: Vol 62, No 6 (2017)
- Pages: 923-927
- Section: Structure of Macromolecular Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191511
- DOI: https://doi.org/10.1134/S106377451706027X
- ID: 191511
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Abstract
A new coordination polymer, {[Cd(BIPA)(1,3-bdc)](DMF)}n, based on bis(4-(1H-imidazol-1- yl)phenyl)amine (BIPA) and 1,3-dicarboxybenzene (1,3-H2bdc) was synthesized and showing 2D → 3D structure via π-π* interaction of BIPA molecules in the nearby networks in the complex. Investigation of photophysical properties showed that the complex exhibits a strong emission in the range of 350–425 nm (λmax = 375 nm upon excitation at 327 nm).
About the authors
Ming-Dao Zhang
Department of Chemistry, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering
Author for correspondence.
Email: matchlessjimmy@163.com
China, Nanjing, Jiangsu, 210044
Bao-Hui Zheng
Institute of Chemical Materials
Email: matchlessjimmy@163.com
China, Mianyang, Sichuan, 621900
Xin Liu
Department of Chemistry, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering
Email: matchlessjimmy@163.com
China, Nanjing, Jiangsu, 210044
Cheng-Yan Huang
Department of Chemistry, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering; School of Chemistry and Life Science
Email: matchlessjimmy@163.com
China, Nanjing, Jiangsu, 210044; Nanjing, Jiangsu, 210089
Bin Wang
Institute of Chemical Materials
Email: matchlessjimmy@163.com
China, Mianyang, Sichuan, 621900
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