A luminescent 2D → 3D Cd complex via π-π* interaction based on bis(4-(1H-imidazol-1-yl)phenyl)amine and 1,3-dicarboxybenzene acid


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Resumo

A new coordination polymer, {[Cd(BIPA)(1,3-bdc)](DMF)}n, based on bis(4-(1H-imidazol-1- yl)phenyl)amine (BIPA) and 1,3-dicarboxybenzene (1,3-H2bdc) was synthesized and showing 2D → 3D structure via π-π* interaction of BIPA molecules in the nearby networks in the complex. Investigation of photophysical properties showed that the complex exhibits a strong emission in the range of 350–425 nm (λmax = 375 nm upon excitation at 327 nm).

Sobre autores

Ming-Dao Zhang

Department of Chemistry, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering

Autor responsável pela correspondência
Email: matchlessjimmy@163.com
República Popular da China, Nanjing, Jiangsu, 210044

Bao-Hui Zheng

Institute of Chemical Materials

Email: matchlessjimmy@163.com
República Popular da China, Mianyang, Sichuan, 621900

Xin Liu

Department of Chemistry, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering

Email: matchlessjimmy@163.com
República Popular da China, Nanjing, Jiangsu, 210044

Cheng-Yan Huang

Department of Chemistry, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering; School of Chemistry and Life Science

Email: matchlessjimmy@163.com
República Popular da China, Nanjing, Jiangsu, 210044; Nanjing, Jiangsu, 210089

Bin Wang

Institute of Chemical Materials

Email: matchlessjimmy@163.com
República Popular da China, Mianyang, Sichuan, 621900

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