Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine
- Authors: Kumar S.1, Andotra S.1, Kaur M.1, Gupta V.K.2, Kant R.2, Pandey S.K.1
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Affiliations:
- Department of Chemistry
- X-ray Crystallographic Laboratory
- Issue: Vol 61, No 5 (2016)
- Pages: 810-814
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/190299
- DOI: https://doi.org/10.1134/S1063774516050126
- ID: 190299
Cite item
Abstract
Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [{(2,4- (CH3)2C6H3O)2PS2}2Fe{NC5H4(C2H5)-4}2] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P21/n, Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.
About the authors
Sandeep Kumar
Department of Chemistry
Email: kpsushil@rediffmail.com
India, Jammu
Savit Andotra
Department of Chemistry
Email: kpsushil@rediffmail.com
India, Jammu
Mandeep Kaur
Department of Chemistry
Email: kpsushil@rediffmail.com
India, Jammu
Vivek K. Gupta
X-ray Crystallographic Laboratory
Email: kpsushil@rediffmail.com
India, Jammu
Rajni Kant
X-ray Crystallographic Laboratory
Email: kpsushil@rediffmail.com
India, Jammu
Sushil K. Pandey
Department of Chemistry
Author for correspondence.
Email: kpsushil@rediffmail.com
India, Jammu
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