Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine


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Abstract

Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [{(2,4- (CH3)2C6H3O)2PS2}2Fe{NC5H4(C2H5)-4}2] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P21/n, Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.

About the authors

Sandeep Kumar

Department of Chemistry

Email: kpsushil@rediffmail.com
India, Jammu

Savit Andotra

Department of Chemistry

Email: kpsushil@rediffmail.com
India, Jammu

Mandeep Kaur

Department of Chemistry

Email: kpsushil@rediffmail.com
India, Jammu

Vivek K. Gupta

X-ray Crystallographic Laboratory

Email: kpsushil@rediffmail.com
India, Jammu

Rajni Kant

X-ray Crystallographic Laboratory

Email: kpsushil@rediffmail.com
India, Jammu

Sushil K. Pandey

Department of Chemistry

Author for correspondence.
Email: kpsushil@rediffmail.com
India, Jammu

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